Double C-H Activation. Dimerization of Esters Catalyzed by RhCl(CO)(PMe3)2 under Irradiation

DOI: 10.1246/cl.1988.683

Source and publish data:

Chemistry Letters p. 683 - 684 (1988)

Update date:2022-08-04

Topics:

Authors:

Sakakura, Toshiyasu

Sodeyama, Touru

Tanaka, Masato

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Article abstract of DOI:10.1246/cl.1988.683

Dehydrogenation of methyl propionate yielded methyl 4-propionyloxybutyrate (head-to-tail dimer) by photocatalysis in the presence of RhCl(CO)PMe3)2 at room temperature.Methyl acrylate is presumed to be an intermediate.

Full text of DOI:10.1246/cl.1988.683

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