Reaction of benzene and benzene with Trimethylsilyl Enol Ethers. A New General Method for α-Sulfonyloxylation of Carbonyl Compounds

DOI: 10.1021/jo00266a020

Source and publish data:

Journal of Organic Chemistry p. 1101 - 1104 (1989)

Update date:2022-08-04

Topics:

Authors:

Moriarty, Robert M.

Penmasta, Raju

Awasthi, Alok K.

Epa, W. Ruwan

Prakash, Indra

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00266a020

Reaction of benzene (1) with trimethylsilyl enol ethers of aromatic ketones 4a-d, alicyclic ketone 7, aliphatic ketone 10, and esters 13a-c in dichloromethane at room temperature gives good yields of α-(tosyloxy)carbonyl compounds 5

Full text of DOI:10.1021/jo00266a020

Products guided by the article

Product name:2-methyl-6-(tosyloxy)cyclohexanone

Cas No:118921-62-3

R&D Labs maybe for 118921-62-3

Jiangxi Lanqi Fine Chemical S&T Co., Ltd.

Contact:+86-21-64891143

Address:XinJiShan Industrial Area, Zhangshu City, JiangXi Province, China
Shanghai Apeptide Co., Ltd.

website:http://www.apeptides.com/en/

Contact:+86-21-60871011

Address:No. 80 Chuanshan Shuyuan Steet,Pudong,Shanghai
Okeanos Tech.Co.,LTD

Contact:+86-10-62651721

Address:29 Yongxing Road, Daxing District,Beijing China
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan

Relevant to this article

Unique sodium dithionite initiated coupling of CF₃CHClBr with 1,3,5-trimethoxybenzene: Synthesis and structure of trifluoromethyl-bis(2,4,6-trimethoxyphenyl)methane

Doi:10.1016/j.jfluchem.2009.02.011
(2009)
Nucleopalladation triggering the oxidative heck reaction: A general strategy to diverse β-indole ketones

Doi:10.1021/ol4027683
(2013)
Erratum: Molecular Imaging of Peroxynitrite with HKGreen-4 in Live Cells and Tissues (Journal of the American Chemical Society (2014) 136 (11728-11734) (DOI: 10.1021/ja504624q)

Doi:10.1021/jacs.6b02642
(2016)
Doi:10.1016/S0020-1693(00)85160-9
(1988)
Conversion from ILCT to LLCT/MLCT excited state by heavy metal ion binding in iridium(III) complexes with functionalized 2,2'-bipyridyl ligands

Doi:10.1021/om900334f
(2009)
Synthesis and properties of imidazo[1,2-a]pyridinium-3-olate. Some revised structures

Doi:10.1016/j.tet.2009.06.116
(2009)

Article Doi