Tetrahedron Letters p. 3311 - 3314 (1988)
Update date:2022-08-02
Topics: Oxidation Asymmetric synthesis Enantiomer Regioselectivity Yield NMR spectroscopy Nucleophile Electrophile Reduction Enantiomeric excess (ee) Chromatography Recrystallization Nucleophilic substitution Optical rotation Deprotection TLC (thin-layer chromatography) HPLC (high-performance liquid chromatography) Protecting group Resolution Leaving group Diastereomers Catalytic asymmetric synthesis Stereocontrol Retrosynthetic analysis Asymmetric Induction Stereochemical Control Asymmetric Hydrogenation Chirality transfer Chiral Catalyst Stereoselectivity Kinetic Resolution Chiral Auxiliary Racemization Dynamic Kinetic Resolution Chiral Environment Desymmetrization Chiral Ligand Prochiral Chiral recognition Stereospecific Reaction Chiral Pool Stereochemical analysis Stereochemical Data Chiral Derivatizing Agent Stereochemical Preference Homochiral Stereochemical Integrity Enantioselective Catalysis Absolute Configuration Enantiopure
Quirion, Jean-Charles
Grierson, David S.
Royer, Jacques
Husson, Henri-Philippe
The enantiospecific synthesis of (+) and (-) isonitramines 7 has been achieved from a common chiral intermediate 5; this key compound was formed by condensation of two molar equivalents of glutaraldehyde with one mole of (-) phenylglycinol.
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(1992)
