Chelate-stabilised Alcohol- and Alkoxo-palladium(II) Complexes derived from the Ligands Ph2PCH2CR2OH (R = Me or H)

DOI: 10.1039/DT9890001193

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1193 - 1196 (1989)

Update date:2022-09-26

Topics:

Authors:

Platt, Andrew W. G.

Pringle, Paul G.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9890001193

The ligands Ph2PCH2CRR'OH form complexes of stoicheiometry PdCl2(Ph2PCH2CRR'OH)2 which are in the neutral form trans- where R,R' = Me or H (2a)-(2c) in CDCl3 solution, and the ionic form where R = R' = Me (4a) or R = Me, R' = H (4b) in CD3OD solution.The complex dissolves in D2O to give an acidic solution of pH 3.9.Treatment of trans- (2a) or (2b) with AgClO4 in acetone gives (6a) or (6b).Deprotonation of (6a) or (6b) with Et3N in CDCl3 or deprotonation of (2a)-(2c) with NaOH in ethanol gave the bis(alkoxo) complexes (7a)-(7c).Deprotonation of (2c) with Et3N in CDCl3 gave a mixture of three Pd species, including the binuclear complex (9).All products have been characterised by a combination of elemental analysis, i.r., (1)H, and (31)P n.m.r. spectroscopy.

Full text of DOI:10.1039/DT9890001193

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:trans-{PdCl₂Ph₂PCH₂CH₂OH}2

Cas No:121918-09-0

R&D Labs maybe for 121918-09-0

Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
Jiangsu Feymer Technology Co., Ltd.

Contact:+86-512-58110132

Address:Fenghuang Town, Zhangjiagang City, Jiangsu Province, China
Luoyang Aoda chemical Co.,Ltd.

Contact:+86-379-67518785 67516588

Address:MiaoWan industry district,YanShi City,Henan,China
Acorn PharmaTech Co., Ltd

Contact:86-25-58619180

Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
ENERGYCO LTD.

Contact:+86-25-83719363

Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China

Relevant to this article

Stereoselective reactions of alkenylpyranosides: The effect of double bond geometry on conformation

Doi:10.1021/ja00220a034
(1988)
Competitive <4+2>-Cycloaddition versus <1,5>-Hydrogen Sigmatropy in a Cycloheptatriene. An Efficient Route to 3-Azatricyclo<5.3.1.0^4,10>undeca-5,8-diene

Doi:10.1021/jo00247a001
(1988)
Synthesis and biological activity of anticoccidial agents: 2,3-diarylindoles

Doi:10.1016/j.bmcl.2009.01.001
(2009)
Phytotoxic effects of selected N-benzyl-benzoylhydroxamic acid metallo-oxygenase inhibitors: Investigation into mechanism of action

Doi:10.1039/c3nj00491k
(2013)
UNEXPECTED REACTIONS OF 1,4-DIAZA-1,3-DIENES UNDER ACYLATING CONDITIONS. A NEW CYCLIZATION TO NON-ACYLATED IMIDAZOLE DERIVATIVES

Doi:10.1016/S0040-4039(00)96577-8
(1987)
Cationic and anionic dinuclear nickel complexes [Ni(N₂S ₂)Ni(dtc)]ⁿ (n=-1, +1) modeling the active site of acetyl-CoA synthase

Doi:10.1246/cl.2009.184
(2009)

Article Doi