Journal of Organic Chemistry p. 1958 - 1960 (1994)
Update date:2022-08-05
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Kiyooka, Syun-ichi
Shiomi, Yasuhiro
Kira, Haruhide
Kaneko, Yuichi
Tanimori, Shinji
In the presence of BF3*OEt2 (0.2 molar equiv), the reactions (-10 deg C, CH2Cl2) of N-Cbz-α-amino aldehydes with allyltrimethylsilane produced pyrrolidines in good yields (70-80percent), with high all-cis stereoselectivity at the C-2, C-3, and C-5 positio
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