Diazadien-Komplexe des Rutheniums. XIII. Bis(diazadien)ruthenium: Isomerisierung, Hydrierung, Metallierung; Struktur eines Kalium(tmeda)2-ruthenats(0)

Article abstract of DOI:10.1016/0022-328X(91)83049-A

Bis(diazadiene)dichlororuthenium (R-DAD)2RuCl2 (1) (R-DAD = RN=CHCH=NR with R = 2,6-xylyl) reacts with 2 mol of potassium in tetrahydrofuran to give the unsaturated (R-DAD)2Ru (2) and its isomer (3), in which one of the o-methyl groups of R is metalated.T