Diazadien-Komplexe des Rutheniums. XIII. Bis(diazadien)ruthenium: Isomerisierung, Hydrierung, Metallierung; Struktur eines Kalium(tmeda)2-ruthenats(0)

DOI: 10.1016/0022-328X(91)83049-A

Source and publish data:

Journal of Organometallic Chemistry p. 445 - 456 (1991)

Update date:2022-08-04

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Authors:

Rosenberger, Volker

Fendesak, Gert

Dieck, Heindrik tom

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Article abstract of DOI:10.1016/0022-328X(91)83049-A

Bis(diazadiene)dichlororuthenium (R-DAD)2RuCl2 (1) (R-DAD = RN=CHCH=NR with R = 2,6-xylyl) reacts with 2 mol of potassium in tetrahydrofuran to give the unsaturated (R-DAD)2Ru (2) and its isomer (3), in which one of the o-methyl groups of R is metalated.T

Full text of DOI:10.1016/0022-328X(91)83049-A

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