A Route to Glycals in the Allal and Gulal Series: Synthesis of the Thiosugar of Esperamicin A1

DOI: 10.1021/jo00294a004

Source and publish data:

Journal of Organic Chemistry p. 1979 - 1981 (1990)

Update date:2022-08-04

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Authors:

Wittman, Mark D.

Halcomb, Randall L.

Danishefsky, Samuel J.

Golik, Jerzy

Vyas, Dolatrai

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Article abstract of DOI:10.1021/jo00294a004

Axial anomeric sulfoxides generated via thiophenol Ferrier rearrangement of glucal and galactal derivatives are used to synthesize glycals of the gulal and allal series.An application of the method led to the synthesis of the esperamicin thiosugar, thereb

Full text of DOI:10.1021/jo00294a004

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