
Journal of Organic Chemistry p. 1979 - 1981 (1990)
Update date:2022-08-04
Topics:
Wittman, Mark D.
Halcomb, Randall L.
Danishefsky, Samuel J.
Golik, Jerzy
Vyas, Dolatrai
Axial anomeric sulfoxides generated via thiophenol Ferrier rearrangement of glucal and galactal derivatives are used to synthesize glycals of the gulal and allal series.An application of the method led to the synthesis of the esperamicin thiosugar, thereb
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