Intermolecular tautomerization of metallacyclic imines to enamines formed from tantalum alkyne complexes and nitriles

DOI: 10.1021/om00119a044

Source and publish data:

Organometallics p. 1665 - 1669 (1990)

Update date:2022-09-26

Topics:

Authors:

Strickler, Jamie R.

Wigley, David E.

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Article abstract of DOI:10.1021/om00119a044

The electrophilic metal center in (DIPP)₃Ta(PhC≡CPh) (1; DIPP = 2,6-diisopropylphenoxide) coordinates a variety of nitriles to afford the η¹-nitrile adducts (DIPP)₃(RC≡N)Ta(PhC≡CPh) (2, R = CH₃; 3, R = CH_2<

Full text of DOI:10.1021/om00119a044

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