Intermolecular tautomerization of metallacyclic imines to enamines formed from tantalum alkyne complexes and nitriles

DOI: 10.1021/om00119a044

Source and publish data:

Organometallics p. 1665 - 1669 (1990)

Update date:2022-09-26

Topics:

Authors:

Strickler, Jamie R.

Wigley, David E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00119a044

The electrophilic metal center in (DIPP)₃Ta(PhC≡CPh) (1; DIPP = 2,6-diisopropylphenoxide) coordinates a variety of nitriles to afford the η¹-nitrile adducts (DIPP)₃(RC≡N)Ta(PhC≡CPh) (2, R = CH₃; 3, R = CH_2<

Full text of DOI:10.1021/om00119a044

Products guided by the article

Product name:(2,6-diisopropylphenoxide)3Ta(CPh=CPhC(=CD₂)ND)

Cas No:126790-11-2

R&D Labs maybe for 126790-11-2

Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.

Contact:+86-417-2927806

Address:yingkou
Jiangxi Huashi Pharmaceutical Co., Ltd

Contact:+86-795-4509628

Address:No.199, Ningbo Avenue, Fengxin industrial park, Fengxin county, Yichun city, Jiangxi
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District
Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
Beijing Wisdom Chemicals Co., Ltd.

Contact:+86-10-52350335

Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China

Relevant to this article

Synthesis of arylurethans of 1,2-dimethy-3-hydroxymethylhdexahydropyridazine as anticonvulsant agents

Doi:10.1016/0223-5234(89)90091-3
(1989)
Highly diastereoselective synthesis of α-trifluoromethylated α-propargylamines by acetylide addition to chiral CF₃- substituted N-tert-butanesulfinyl ketimines

Doi:10.1016/j.tetasy.2010.11.028
(2010)
A series of Cd(II) complexes with ππ stacking and hydrogen bonding interactions: Structural diversities by varying the ligands

Doi:10.1016/j.jssc.2010.11.016
(2011)
Aryl(triethyl)silanes for Biaryl and Teraryl Synthesis by Copper(II)-Catalyzed Cross-Coupling Reaction

Doi:10.1002/anie.201608667
(2016)
Synthetic methodology for the preparation of trans- and cis-2,9-disubstituted oxonanes

Doi:10.1016/S0040-4039(01)93860-2
(1989)
SYNTHESIS AND NMR STUDY OF 7-ARYL-1,2,4-TRIAZOLO-<1,5-a>-1,3,5-TRIAZINES

Doi:10.1007/BF00962149
(1989)

Article Doi