Tetrahedron Letters p. 4731 - 4734 (1989)
Update date:2022-07-29
Topics:
Walkington, Andrew J.
Whiting, Donald A.
Aryloxymethylene radicals generated by decarboxilation of the thiohydroxamate esters derived from acids (8a), (10a), and (12) undergo 6-endo cyclisation yielding (9), (11), and (14) respectively, mimicking the unusual biosynthetic reactions involved in formation of (1), (3), and (4) in nature.
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