STUDIES IN MACROLIDE SYNTHESIS: A HIGHLY STEREOSELECTIVE SYNTHESIS OF (+)-(9S)-DIHYDROERYTHRONOLIDE A USING MACROCYCLIC STEREOCONTROL.

DOI: 10.1016/S0040-4039(00)70726-X

Source and publish data:

Tetrahedron Letters p. 7463 - 7466 (1989)

Update date:2022-08-02

Topics: Stereoselective synthesis Macrocyclic Stereocontrol

Authors:

Paterson, Ian

Rawson, David J.

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Article abstract of DOI:10.1016/S0040-4039(00)70726-X

(+)-(9S)-Dihydroerythronolide A, 1, is prepared in 8 steps from macrolide 3 by exploiting the conformational preferences of the (5E,11E)-diene intermediate 2.The stereocontrolled introduction of the hydroxyl groups at C₆, C₁₁, and C<

Full text of DOI:10.1016/S0040-4039(00)70726-X

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