Journal of the American Chemical Society p. 3577 - 3583 (1980)
Update date:2022-07-29
Topics:
Wilson, Stephen R.
Georgiadis, Gregory M.
Khatri, Hiralal N.
Bartmess, John E.
The reaction of 1,3-dithiolanes with n-butyllithium results in fragmentation to the corresponding thiocarbonyl compound followed by furhter reaction with n-butyllithium.All four types of thiocarbonyl reactions are observed: reduction, S-addition, C-addition, double addition.Synthetic applications of this reaction for the synthesis of secondary mercaptans and 1,2-carbonyl transposition (23 -> 24a-c) are described.
View MoreContact:+49-4101-3053-0
Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Contact:+86-371-86058576
Address:NO.32, Jingsan Road, Zhengzhou, China
Daqing E-shine Chemical Co.,LTD
Contact:0086-024-31285112
Address:Hongweiyuan area, Ranghulu district
Taizhou Elitechemie MediPharma Technology Co.,Ltd.
Contact:+86-523-86810021
Address:Building G14,NO.1 Avenue,China Medical City, Taizhou, Jiangsu,China
Changzhou Ruiping Chemical Co., Ltd
website:http://www.wishchem.com
Contact:+86-519-82324280
Address:No.288-1 Huacheng Road, Jintan
Doi:10.1021/ol2007633
(2011)Doi:10.1021/bc1004526
(2011)Doi:10.1021/ol200649u
(2011)Doi:10.1055/s-0030-1258390
(2011)Doi:10.1016/S0040-4020(01)89785-4
(1990)Doi:10.1021/ml2000356
(2011)
