
Journal of the Chemical Society. Perkin transactions I p. 1101 - 1106 (1990)
Update date:2022-08-04
Topics:
Kawasaki, Tomomi
Nonaka, Yoshinori
Ohtsuka, Hiroaki
Sato, Hiroshi
Sakamoto, Masanori
The Wittig reaction of 1-acetyl-2-methoxy- (1) and 1-acetyl-2-hydroxyindol-3(2H)-one (2) with stabilized and semistabilized ylides gave predominantly 3-alkylidenedihydroindoles (4), (7), and (13) with (Z)-stereochemistry.When the Wittig reaction was carried out under more drastic conditions, the Wittig products (4) and (7) isomerized to afford 3-alkylindoles (5) and the indol-2-one (8), respectivily.These isomerizations are also described.
View MoreShenyang Mole pharmaceutical Technology Development Co.,Ltd
Contact:+86-24-31204918/13889278616
Address:No.44, wanliutang road, shenhe District of Shenyang
Shanghai Standard Biotech Co., Ltd.
Contact:+86-18502101150
Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)
Contact:+86-512-69598882
Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
website:http://www.shochem.com
Contact:021-50800795
Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Tianjin Ji Ping Jia Chemical Co., Ltd.
Contact:18622448868
Address:tianjin
Doi:10.1016/j.molstruc.2011.01.016
(2011)Doi:10.1021/acs.orglett.9b00722
(2019)Doi:10.1016/j.jfluchem.2011.01.003
(2011)Doi:10.1002/anie.201702950
(2017)Doi:10.1021/ic301866y
(2012)Doi:10.1021/jo00306a014
(1990)