ORTHO LITHIATION DIRECTED BY AMINO GROUPS ON SILICON IN PHENYLSILANE DERIVATIVES

DOI: 10.1016/0040-4039(90)80186-P

Source and publish data:

Tetrahedron Letters p. 2925 - 2928 (1990)

Update date:2022-08-05

Topics:

Authors:

Tamao, Kohei

Yao, Hajime

Tsutsumi, Yasushi

Abe, Hideyuki

Hayashi, Takashi

Ito, Yoshihiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(90)80186-P

Phenylsilanes, which contain trimethylethylenediamino (Me2NCH2CH2NMe-) group(s) on silicon, undergo selective ortho lithiation by treatment with t-BuLi, providing a new method for the synthesis of ortho substituted phenylsilane derivatives.

Full text of DOI:10.1016/0040-4039(90)80186-P

Products guided by the article

Product name:(Isopropoxy-methyl-trimethylsilanylmethyl-silanyl)-benzene

Cas No:129353-69-1

R&D Labs maybe for 129353-69-1

NanJing KaiHeng Chemical CO., LTD.

Contact:+86-25-85768391

Address:RM.1704, D, WANDA PLAZA, NO.110, MIDDLE JIANGDONG ROAD, NANJING, CHINA
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
Shandong Xinke Petrochemical Co., Ltd.

Contact:+86-546-7277016

Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:
Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road

Relevant to this article

Development of an 'Overmethylation' Strategy for Corrin Synthesis. Multi-enzyme Preparation of Pyrrocorphins

Doi:10.1039/c39900000593
(1990)
Larock heteroannulation of 2-bromoanilines with internal alkynes via ligand and salt free Pd/C catalysed reaction

Doi:10.1016/j.tetlet.2011.02.044
(2011)
Synthesis and chemical reactivity of C-5 substituted 6,7-bis-(hydroxymethyl)-1H-pyrrolizine biscarbamate tumor inhibitors [1]

Doi:10.1002/jhet.5570270440
(1990)
Asymmetric synthesis of malic acid-type synthons VIA chiral norephedrine-derived oxazolidines

Doi:10.1016/S0040-4020(01)89766-0
(1990)
Double complex salts with [Ru(NH₃)₅Cl]²⁺ cation and [OsCl₆]^2- anion: Synthesis and properties. Crystal structure of [Ru(NH₃)₅Cl]₂[OsCl ₆]Cl₂

Doi:10.1134/S0036023610090032
(2010)
Substituted phenyl triazoles as selective inhibitors of 11β-hydroxysteroid dehydrogenase type 1

Doi:10.1016/j.bmcl.2011.01.125
(2011)

Article Doi