ORTHO LITHIATION DIRECTED BY AMINO GROUPS ON SILICON IN PHENYLSILANE DERIVATIVES

DOI: 10.1016/0040-4039(90)80186-P

Source and publish data:

Tetrahedron Letters p. 2925 - 2928 (1990)

Update date:2022-08-05

Topics:

Authors:

Tamao, Kohei

Yao, Hajime

Tsutsumi, Yasushi

Abe, Hideyuki

Hayashi, Takashi

Ito, Yoshihiko

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Article abstract of DOI:10.1016/0040-4039(90)80186-P

Phenylsilanes, which contain trimethylethylenediamino (Me2NCH2CH2NMe-) group(s) on silicon, undergo selective ortho lithiation by treatment with t-BuLi, providing a new method for the synthesis of ortho substituted phenylsilane derivatives.

Full text of DOI:10.1016/0040-4039(90)80186-P

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