NICKEL-CATALYZED REACTIONS OF THIAZOLES, ISOXAZOLES, OXAZOLINES AND THIAZOLINES WITH GRIGNARD REAGENTS

DOI: 10.3987/COM-89-S86

Source and publish data:

Heterocycles p. 929 - 937 (1990)

Update date:2022-08-03

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Authors:

Wenkert, Ernest

Han, Aili

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Article abstract of DOI:10.3987/COM-89-S86

Grignard reagents convert thiazoles, isoxazoles, oxazolines and thiazolines into N-vinylimines, β-amino-α,β-unsaturated ketones, tetrahydrooxazoles and tetrahydrothiazoles, respectively, under the influence of phosphine-ligated nickel species.The reaction characteristics and the uncatalyzed reactions are described.

Full text of DOI:10.3987/COM-89-S86

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