Monatshefte fur Chemie p. 793 - 802 (1990)
Update date:2022-08-05
Topics:
Hengge, Edwin
Kalchauer, Wilfried
Disilane dervatives undergo disproportionation reactions to polysilanes.Investigated were 1,2-dimethyldisilane and 1,2-dimethyltetrachlorodisilane with catalysts like NH4Cl, AgCN, and Na-cyanamide.In case of 1,2-dimethylsilane, with more than catalytic amounts of NH4Cl, a nitrogen containing polysilane is formed.Two new compounds MeSiH(NCO)2 and Me2Si2(NCO)4 were synthesized and characterized.The last one leads to a polymer at heating.Additionally an electrochemical formation of polydimethylsilane is described.
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