Methoxylation of Enolizable Steroidal 4-Ene-3-ones using Hypervalent Iodine

DOI: 10.1039/c39860001092

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Journal of the Chemical Society. Chemical communications p. 1092 - 1093 (1986)

Update date:2022-07-29

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Authors:

Numazawa, Mitsuteru

Ogata, Mieko

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Article abstract of DOI:10.1039/c39860001092

Reaction of androst-4-ene-3,17-dione (1) with o-iodosylbenzoic acid in methanolic potassium hydroxide gave the methoxylated products, the 4- and 6β-methoxides (2) and (3), along with the dehydrogenated compound, the 4,6-dienone (4).

Full text of DOI:10.1039/c39860001092

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