2-(N-Methylanilino)-2-phenylthioacetonitrile: a Useful Reagent for Preparation of Conjugated α-Amino Alkenenitriles via Tandem Alkylation and Dehydrosulphenylation

DOI: 10.1039/P19900003365

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3365 - 3367 (1990)

Update date:2022-08-02

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Authors:

Fang, Jim-Min

Chen, Chih-Cheng

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Article abstract of DOI:10.1039/P19900003365

Alkylation of the anion of 2-(N-methylanilino)-2-phenylthioacetonitrile 1 with halogenoalkanes resulted in concurrent elimination of benzenethiol to give conjugated α-aminoalkenenitriles of 2E-configuration.Counterattack by bromide and benzenethiolate ion

Full text of DOI:10.1039/P19900003365

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