Diastereodifferentiation in SN2' Additions of Methylcuprates to Nonracemic Acyclic Vinyloxiranes

DOI: 10.1021/jo00006a049

Source and publish data:

Journal of Organic Chemistry p. 2225 - 2234 (1991)

Update date:2022-07-30

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Authors:

Marshall, James A.

Blough, Bruce E.

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Article abstract of DOI:10.1021/jo00006a049

S_N2' additions of Me2CuLi, MeCu(CN)Li, and Me2Cu(CN)Li2 to the 2S and 2R alkoxy cis-(Z)- and -(E)-vinyloxiranes 8, 9, 13, and 14 were examined as possible routes to acyclic subunits of polypropionate natural products.Highest anti:syn ratios wer

Full text of DOI:10.1021/jo00006a049

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