Diastereodifferentiation in SN2' Additions of Methylcuprates to Nonracemic Acyclic Vinyloxiranes

DOI: 10.1021/jo00006a049

Source and publish data:

Journal of Organic Chemistry p. 2225 - 2234 (1991)

Update date:2022-07-30

Topics:

Authors:

Marshall, James A.

Blough, Bruce E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00006a049

S_N2' additions of Me2CuLi, MeCu(CN)Li, and Me2Cu(CN)Li2 to the 2S and 2R alkoxy cis-(Z)- and -(E)-vinyloxiranes 8, 9, 13, and 14 were examined as possible routes to acyclic subunits of polypropionate natural products.Highest anti:syn ratios wer

Full text of DOI:10.1021/jo00006a049

Products guided by the article

Product name:(E)-(2S,5S)-1-Benzyloxy-3,5-dimethyl-hept-3-ene-2,6-diol

Cas No:132488-13-2

R&D Labs maybe for 132488-13-2

EGBERT CORPORATION

Contact:+86 18616952870

Address:Area
Ji'an Kexin Trade Co., Ltd.(expird)

Contact:86-0796-8187704 18507063190

Address:ji'an jiangxi
Suzhou ATL Chemical Co.,ltd

Contact:+86-0512-69209969

Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
Daqing New Century Fine Chemical Co., Ltd.(expird)

Contact:010-57126694

Address:No.39, jinxing cun, honggang district

Relevant to this article

ASYMMETRIC SYNTHESIS OF (R) AND (S)-4-HYDROXY-2-CYCLOHEXENONE AND DERIVATIVES

Doi:10.1016/S0040-4039(00)97138-7
(1990)
Synthesis and characterization of a novel ester-based nucleoamino acid for the assembly of aromatic nucleopeptides for biomedical applications

Doi:10.1016/j.ijpharm.2011.06.007
(2011)
A facile and efficient carbodiimide-mediated synthesis of dihydroquinazolines via a tandem nucleophilic addition-intramolecular hetero conjugate addition annulation strategy

Doi:10.1016/0040-4039(95)02130-2
(1996)
Catalytic enantioselective halolactonization of enynes and Alkenes

Doi:10.1002/chem.201103809
(2012)
Pd-catalyzed C-H fluorination with nucleophilic fluoride

Doi:10.1021/ol301739f
(2012)
Gold-catalyzed cascade cyclizations of 1,6-diynyl carbonates to benzo[b]fluorenes involving arylation of oxocarbenium ion intermediates and decarboxylative etherification

Doi:10.1002/anie.201201799
(2012)

Article Doi