Thermal rearrangement of 9-benzyl-10-aza-9-thiaphenanthrenes

DOI: 10.1016/S0040-4039(00)97232-0

Source and publish data:

Tetrahedron Letters p. 7021 - 7022 (1990)

Update date:2022-08-03

Topics:

Authors:

Shimizu Shimizu

Ikedo Ikedo

Hamada Hamada

Matsumoto

Ozawa Ozawa

Kataoka Kataoka

Hori Hori

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Article abstract of DOI:10.1016/S0040-4039(00)97232-0

9-Benzyl-10-aza-9-thiaphenanthrenes (3) generated from 9-benzyl-10-aza-9-thiaphenanthrenium salts (2) by treatment with base underwent thermal 1,2-benzyl migration to give the corresponding 6-benzyl-6H-dibenzo[c,e] [1,2]thiazines (4).

Full text of DOI:10.1016/S0040-4039(00)97232-0

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