Reductive Carbonylation of Alkenes using Zwitterionic Rhodium Complexes as Catalysts

DOI: 10.1039/c39910000233

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 233 - 234 (1991)

Update date:2022-09-26

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Authors:

Zhou, Jian-Qiang

Alper, Howard

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Article abstract of DOI:10.1039/c39910000233

Alkenes react with carbon monoxide, sodium borohydride, propan-2-ol and a catalytic amount of Rh(cod)(η⁶-PhBPh3) (cod = cyclooctadiene) to give alcohols in fine yields; high regioselectivity for the branched or linear alcohol is usually observed, depending on the organic substrate.

Full text of DOI:10.1039/c39910000233

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