SYNTHETIC USEFULNESS OF SILYL THIOKETONES: FUNCTIONALIZATION OF THEIR PRIMARY ADDUCTS THROUGH DESILYLATION AND TRAPPING BY CARBON ELECTROPHILES.

DOI: 10.1016/S0040-4039(00)74895-7

Source and publish data:

Tetrahedron Letters p. 815 - 818 (1991)

Update date:2022-08-03

Topics:

Authors:

Bonini, Bianca F.

Masiero, Stefano

Mazzanti, Germana

Zani, Paolo

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Article abstract of DOI:10.1016/S0040-4039(00)74895-7

Desilylation of either α-silyl sulphides or silyl dihydrothiopyrans (easily obtained from silyl thiones as primary adducts), when performed in the presence of carbon electrophiles (aldehydes or ketones), offers an easy entry to carbofunctionalised products.

Full text of DOI:10.1016/S0040-4039(00)74895-7

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