SYNTHETIC USEFULNESS OF SILYL THIOKETONES: FUNCTIONALIZATION OF THEIR PRIMARY ADDUCTS THROUGH DESILYLATION AND TRAPPING BY CARBON ELECTROPHILES.

DOI: 10.1016/S0040-4039(00)74895-7

Source and publish data:

Tetrahedron Letters p. 815 - 818 (1991)

Update date:2022-08-03

Topics:

Authors:

Bonini, Bianca F.

Masiero, Stefano

Mazzanti, Germana

Zani, Paolo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)74895-7

Desilylation of either α-silyl sulphides or silyl dihydrothiopyrans (easily obtained from silyl thiones as primary adducts), when performed in the presence of carbon electrophiles (aldehydes or ketones), offers an easy entry to carbofunctionalised products.

Full text of DOI:10.1016/S0040-4039(00)74895-7

Products guided by the article

Product name:2-Methylsulfanyl-2-phenyl-1-p-tolyl-ethanol

Cas No:133810-16-9

R&D Labs maybe for 133810-16-9

Yantai Derun Liquid Crystal Materials Co. Ltd.

website:http://www.ytderun.com

Contact:86-535-6300169

Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Xiamen Hisunny Chemical Co.,Ltd

website:http://www.hisunnychem.com

Contact:+86-592-3327115

Address:Unit 603,No.879,Xiahe Road,Meixin Building,Xiamen,China
Shijiazhuang Yunxuan Im&Export Co.,Ltd.

Contact:+86-311-83037514

Address:No.6 Hongbin Road
Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Taizhou Green Peptide Trading Co., Ltd.

Contact:13736652831

Address:Room 1501, No71, Yuehe Road, Taizhou City, Zhejiang Province, China

Relevant to this article

A Series of hyperbranched polytriazoles containing perfluoroaromatic rings from AB₂-type monomers: Convenient syntheses by click chemistry under copper(I) catalysis and enhanced optical nonlinearity

Doi:10.1002/asia.201100379
(2011)
A formal synthesis of valiolamine from myo-inositol

Doi:10.1016/j.tet.2011.08.027
(2011)
An oxidative coupling route to macrocyclic thiophenes and its application in the synthesis of a donor/acceptor hybrid molecule

Doi:10.1039/c1cc14664e
(2011)
Design, Synthesis, and Biological Evaluation of 1-[(Biarylmethyl)methylamino]-2-(2,4-difluorophenyl)-3-(1H-1,2,4-triazol-1-yl)propan-2-ols as Potent Antifungal Agents: New Insights into Structure-Activity Relationships

Doi:10.1002/cmdc.201100262
(2011)
Optimization of synthetic conditions for the preparation of dihomo-γ-linolenic acid from γ-linolenic acid

Doi:10.1007/s11746-008-1320-0
(2009)
Formal Total Synthesis of (±)-Rhazinal: Evaluating the Radical Approach

Doi:10.1055/s-0036-1588956
(2017)

Article Doi