1-1-Dichloro-2,2,2-trifluoroethyllithium in asymmetric synthesis, II. A route to optically pure 4,4,4-trifluoro-2-hydroxybutanoic acid

DOI: 10.1055/s-1991-26412

Source and publish data:

Synthesis p. 177 - 180 (1991)

Update date:2022-08-04

Topics:

Authors:

Solladie-Cavallo

Quazzotti

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Article abstract of DOI:10.1055/s-1991-26412

On addition of pre-cooled butyllithium to 1,1,1-trichloro-2,2,2-trifluoroethane (1) in diethyl ether at -125°C, 1,1-dichloro-2,2,2-trifluoroethyllithium (2) is formed, addition of o-substituted benzaldehydes yields 1-aryl-2,2-dichloro-3,3,3-trifluoropropa

Full text of DOI:10.1055/s-1991-26412

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