FORMATION OF ALKYLATED TRIPHENYLSILYLALKENES FROM THE REACTION OF TRIPHENYLSILYL-SUBSTITUTED OXIRANYL ANION WITH ORGANOALUMINIUM REAGENTS

DOI: 10.1016/0040-4039(91)85085-J

Source and publish data:

Tetrahedron Letters p. 2783 - 2786 (1991)

Update date:2022-09-26

Topics: Reaction Formation Experimental

Authors:

Taniguchi, Masahiko

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/0040-4039(91)85085-J

Oxiranyl anion generated from 2-methyl-3-triphenylsilyloxirane and sec-BuLi gave (E)-2-triphenylsilyl-2-butene or (E,E)-3-triphenylsilyl-2,4-nonadiene upon treatment with trimethylaluminium or (E)-1-hexenyldiisobutylaluminium.

Full text of DOI:10.1016/0040-4039(91)85085-J

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