Decomposition of bis( silyldiazomethyl) polysilanes: formation of polysilabicyclo(l.m.n)alkane derivatives

DOI: 10.1016/0022-328X(95)00324-J

Source and publish data:

Journal of Organometallic Chemistry p. 99 - 112 (1995)

Update date:2022-09-26

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Authors:

Ando, Wataru

Sugiyama, Mitsuru

Suzuki, Tomohisa

Kato, Chikako

Arakawa, Yusuke

Kabe, Yoshio

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Article abstract of DOI:10.1016/0022-328X(95)00324-J

The photolysis of bis(trimethylsilyldiazomethyl)disilane (4a) in tert-butyl alcohol provided the tert-butyl alcohol adducts S, 6, 7, 8 and 9.The structures of these products revealed the stepwise formation of asymmetric silenes as intermediates.Gas-phase

Full text of DOI:10.1016/0022-328X(95)00324-J

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