STEREOSELECTIVE -SIGMATROPIC REARRANGEMENT OF CHIRAL AMINE OXIDES DERIVED FROM AMINO ACIDS

DOI: 10.1016/0040-4039(91)80017-Z

Source and publish data:

Tetrahedron Letters p. 4481 - 4482 (1991)

Update date:2022-08-03

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Authors:

Reetz, M. T.

Lauterbach, E. H.

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Article abstract of DOI:10.1016/0040-4039(91)80017-Z

Chiral γ-N,N-dibenzylamino α,β-unsaturated esters 1 are oxidized by m-chloroperbenzoic acid to form the amine oxides 2 which undergo a <2,3>-sigmatropic rearrangement with complete 1,3-transfer of chirality.Key Words: Amino acids, amine oxides, <2,3>-sigm

Full text of DOI:10.1016/0040-4039(91)80017-Z

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