Journal of Organic Chemistry p. 5286 - 5296 (2012)
Update date:2022-07-30
Topics:
Orellana, Arturo
Pandey, Sushil K.
Carret, Sebastien
Greene, Andrew E.
Poisson, Jean-Francois
An efficient synthesis of (-)-kainic acid, through a high-pressure-promoted Diels-Alder cycloaddition of a vinylogous malonate derived from 4-hydroxyproline, is described. The bicyclic adduct could be converted into the natural product with complete stereocontrol.
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