Rearrangement of 3-aryl-4-methylmorpholinium-4-methylides

DOI: 10.1055/s-1991-26627

Source and publish data:

Synthesis p. 996 - 998 (1991)

Update date:2022-07-29

Topics:

Authors:

Kitano Kitano

Shirai Shirai

Sato Sato

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Article abstract of DOI:10.1055/s-1991-26627

Fluoride-ion induced desilylation reaction of 3-Aryl-4-methyl-4[(trimethylsilyl)methyl]morpholinium iodides 5a, b gave 4-methyl-6-phenyl-1,4-oxazepane (9a, Stevens rearrangement product) from 5a, and 10-methoxy-2-methyl-1,2,3,4,6,11a-hexahydro-5,2-benzoxa

Full text of DOI:10.1055/s-1991-26627

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