Reaction of pyranoid and furanoid aldonolactones with chloromethyltrimethylsilane-derived reagents

DOI: 10.1016/0008-6215(91)80007-A

Source and publish data:

Carbohydrate Research p. 79 - 92 (1991)

Update date:2022-08-03

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Authors:

Glanzer Glanzer

Csuk Csuk

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Article abstract of DOI:10.1016/0008-6215(91)80007-A

Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones. Reaction of pyranoid and furanoid aldonolactones with trimethylsilylmethyl-lithium provides a convenient route to carbon-chain-elongated methyl ketones. Reaction of the lactones with chloro(trimethylsilyl)methyl-lithium gives the corresponding chloromethylketones.

Full text of DOI:10.1016/0008-6215(91)80007-A

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