GENERATION OF PERFLUOROALKYL RADICALS AT LOW TEMPERATURE BY TELLUROLATE MEDIATED ELECTRON TRANSFER

DOI: 10.1016/0040-4039(91)80124-O

Source and publish data:

Tetrahedron Letters p. 7425 - 7426 (1991)

Update date:2022-08-03

Topics:

Authors:

Uneyama, Kenji

Kanai, Masatomi

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Article abstract of DOI:10.1016/0040-4039(91)80124-O

Perfluoroalkyl-telluration of olefins has been performed at low temperatures by the electron-transfer reaction from sodium tellurolate to perfluoroalkyl halides followed by S_RN1 reaction, meanwhile perfluoroalkyl-ethoxylation occurred with isobutyl vinyl ether via the subsequent substitution of the telluro group with ethoxylate in the conditions.

Full text of DOI:10.1016/0040-4039(91)80124-O

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