Anion Reactions of 1,3-Dithiane 1,3-Dioxide with Carbonyl Compounds: High Diastereoselectivity with Aromatic Aldehydes under Conditions of Equilibrium Control

DOI: 10.1021/jo00112a042

Source and publish data:

Journal of Organic Chemistry p. 2174 - 2182 (1995)

Update date:2022-07-29

Topics:

Authors:

Aggarwal, Varinder K.

Franklin, Richard

Maddock, John

Evans, Graham R.

Thomas, Abraham

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00112a042

We have investigated the anion chemistry of trans-1,3-dithiane 1,3-dioxide (4) with aldehydes and ketones, and we have found that this reagent undergoes highly selective addition reactions with aromatic aldehydes but only when reactions are under equilibr

Full text of DOI:10.1021/jo00112a042

Products guided by the article

Product name:1-(RS)-3-(RS)-α-(SR)-α-(3-Methoxyphenyl)-1,3-dioxo-1,3-dithiane-2-methanol

Cas No:139630-39-0

R&D Labs maybe for 139630-39-0

Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）

Contact:86-531-88072280

Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China
Jurong Huaheng Natural Biological Products Factory

website:http://www.risebiochem.com

Contact:+86-13921007726

Address:Chuncheng town,Jurong city,Jiangsu province,China
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd

Contact:+86-533-5415882

Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china

Relevant to this article

Purines. XLIX. Synthesis and proton nuclear magnetic resonance study of 3,7-dialkylxanthines and 1,3,7-trialkylxanthines

Doi:10.1248/cpb.39.2855
(1991)
A practical synthesis of 2-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-2- (piperidin-4-yl)-1H-imidazol-1-yl}- N, N -dimethylethanamine

Doi:10.1055/s-0031-1290371
(2012)
D-ring modified novel isosteviol derivatives: Design, synthesis and cytotoxic activity evaluation

Doi:10.1016/j.bmcl.2012.07.083
(2012)
Discovery of a novel non-steroidal GR antagonist with in vivo efficacy in the olanzapine-induced weight gain model in the rat

Doi:10.1016/j.bmcl.2012.10.074
(2012)
Study of regioselectivity of reactions between 3(5)-aminopyrazoles and 2-acetylcycloalkanones

Doi:10.1134/S1070428012080131
(2012)
Orally active cephalosporins. IV. Synthesis, antibacterial activity and oral absorption of 3-(1H-1,2,3-triazol-4-yl)thiomethylthio-cephalosporins

Doi:10.1248/cpb.41.758
(1993)

Article Doi