Anion Reactions of 1,3-Dithiane 1,3-Dioxide with Carbonyl Compounds: High Diastereoselectivity with Aromatic Aldehydes under Conditions of Equilibrium Control

DOI: 10.1021/jo00112a042

Source and publish data:

Journal of Organic Chemistry p. 2174 - 2182 (1995)

Update date:2022-07-29

Topics:

Authors:

Aggarwal, Varinder K.

Franklin, Richard

Maddock, John

Evans, Graham R.

Thomas, Abraham

et al. et al.

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Article abstract of DOI:10.1021/jo00112a042

We have investigated the anion chemistry of trans-1,3-dithiane 1,3-dioxide (4) with aldehydes and ketones, and we have found that this reagent undergoes highly selective addition reactions with aromatic aldehydes but only when reactions are under equilibr

Full text of DOI:10.1021/jo00112a042

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