Development of a chiral stabilised azomethine ylid. A chiral relay system

DOI: 10.1016/S0957-4166(00)82350-2

Source and publish data:

Tetrahedron Asymmetry p. 169 - 172 (1991)

Update date:2022-07-30

Topics:

Authors:

Anslow Anslow

Harwood Harwood

Phillips

Watkin Watkin

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Article abstract of DOI:10.1016/S0957-4166(00)82350-2

The chiral, stabilised azomethine ylids (2) derived from (R)-2-phenylglycinol has been demonstrated to undergo enantioselective 1,3-dipolar cycloaddition reactions with a range of alkene and alkyne dipolarophiles.

Full text of DOI:10.1016/S0957-4166(00)82350-2

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Product name:2(R),6(R),7(R),8(S)-N-<(5'(R)-phenylmorpholin-2-onyl)methyl>-2-phenyl-1-aza-4-oxa<4.3.0^1,6>bicyclononan-5-one-7,8-dicarboximide

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