A Novel Skeletal Rearrangement of 2-Azabicyclohept-5-ene-3-carboxylic Acid Derivatives into 2-Oxabicyclo-oct-7-en-3-ones under Acidic Conditions

DOI: 10.1246/bcsj.65.61

Source and publish data:

Bulletin of the Chemical Society of Japan p. 61 - 65 (1992)

Update date:2022-07-29

Topics:

Authors:

Kobayashi, Tomoshige

Ono, Katsuhiko

Kato, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.65.61

The reaction of ethyl 2-azabicyclo<2.2.1>hept-5-ene-3-carboxylate with aroyl chloride and the subsequent hydrolysis of the ester group provided 2-aroyl-2-azabicyclo<2.2.1>hept-5-ene-3-carboxylic acid derivatives, which underwent a stereospecific rearrange

Full text of DOI:10.1246/bcsj.65.61

Products guided by the article

Product name:2-Azabicyclo[2.2.1]hept-5-ene-3-carboxylic acid, 2-(4-nitrobenzoyl)-, ethyl ester, endo-

Cas No:139952-80-0

R&D Labs maybe for 139952-80-0

Zhejiang Kaili Industrial Co., Ltd

Contact:+86-571-85241926

Address:lantian business center,No.18 Moganshan Road
UNION PHARMPRO CO.,LTD

Contact:18710867521(wechat)

Address:Rm10516,Galaxy Tech Building #2,No.25 Tangyan Rd,Hi-Tech Zone,Xi'an, China
HANGZHOU FOREWIN PHARMA CO., LTD

Contact:+86-571-89053961

Address:hangzhou
Suzhou Jingye Medicine & Chemical Co., Ltd

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China

Relevant to this article

Tandem-type Pd(ii)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: A novel route to 4-aryl-2-quinolinones

Doi:10.1039/c2cc30600j
(2012)
Investigation into the regiochemistry of some pyrazoles derived from 1, 3-dipolar cycloaddition of acrylonitrile with some nitrilimines: Theoretical and experimental studies

Doi:10.4067/S0717-97072011000400010
(2011)
Synthesis, characterization and drug-likeness predictions of 1,3-thiazole and benzothiazole derivatives

Doi:10.13005/ojc/340660
(2018)
Cyclisation of 2-(2-aminophenyl)quinazolin-4(3H)-one reexamined: Formation of isomeric angular fused quinazolinoquinazolinones and their spectroscopic identification

Doi:10.1016/j.tetlet.2012.03.055
(2012)
Doi:10.1021/jo01037a527
(1963)
Stable Isotope-Labeled RNA Phosphoramidites to Facilitate Dynamics by NMR

Doi:10.1016/bs.mie.2015.06.013
(2015)

Article Doi