A Novel Skeletal Rearrangement of 2-Azabicyclohept-5-ene-3-carboxylic Acid Derivatives into 2-Oxabicyclo-oct-7-en-3-ones under Acidic Conditions

DOI: 10.1246/bcsj.65.61

Source and publish data:

Bulletin of the Chemical Society of Japan p. 61 - 65 (1992)

Update date:2022-07-29

Topics:

Authors:

Kobayashi, Tomoshige

Ono, Katsuhiko

Kato, Hiroshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.65.61

The reaction of ethyl 2-azabicyclo<2.2.1>hept-5-ene-3-carboxylate with aroyl chloride and the subsequent hydrolysis of the ester group provided 2-aroyl-2-azabicyclo<2.2.1>hept-5-ene-3-carboxylic acid derivatives, which underwent a stereospecific rearrange

Full text of DOI:10.1246/bcsj.65.61

Products guided by the article

Product name:2-Azabicyclo[2.2.1]hept-5-ene-3-carboxylic acid, 2-(4-nitrobenzoyl)-, ethyl ester, endo-

Cas No:139952-80-0

R&D Labs maybe for 139952-80-0

Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Zhejiang Hoshine Silicon Industry Co., Ltd.

Contact:86-573-89179966

Address:Zhapu Town, Pinghu City, Zhejiang, China
NINGXIA DARONG CHEMICALS & METALLURGY CO.,LTD.

Contact:86-952-2179751

Address:Darong Road, Dawukou, Shizuishan, Ningxia 753001, China
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED

Contact:+86-0532-82683616

Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China

Relevant to this article

Tandem-type Pd(ii)-catalyzed oxidative Heck reaction/intramolecular C-H amidation sequence: A novel route to 4-aryl-2-quinolinones

Doi:10.1039/c2cc30600j
(2012)
Investigation into the regiochemistry of some pyrazoles derived from 1, 3-dipolar cycloaddition of acrylonitrile with some nitrilimines: Theoretical and experimental studies

Doi:10.4067/S0717-97072011000400010
(2011)
Synthesis, characterization and drug-likeness predictions of 1,3-thiazole and benzothiazole derivatives

Doi:10.13005/ojc/340660
(2018)
Cyclisation of 2-(2-aminophenyl)quinazolin-4(3H)-one reexamined: Formation of isomeric angular fused quinazolinoquinazolinones and their spectroscopic identification

Doi:10.1016/j.tetlet.2012.03.055
(2012)
Doi:10.1021/jo01037a527
(1963)
Stable Isotope-Labeled RNA Phosphoramidites to Facilitate Dynamics by NMR

Doi:10.1016/bs.mie.2015.06.013
(2015)

Article Doi