A Novel Skeletal Rearrangement of 2-Azabicyclohept-5-ene-3-carboxylic Acid Derivatives into 2-Oxabicyclo-oct-7-en-3-ones under Acidic Conditions

DOI: 10.1246/bcsj.65.61

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Bulletin of the Chemical Society of Japan p. 61 - 65 (1992)

Update date:2022-07-29

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Authors:

Kobayashi, Tomoshige

Ono, Katsuhiko

Kato, Hiroshi

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Article abstract of DOI:10.1246/bcsj.65.61

The reaction of ethyl 2-azabicyclo<2.2.1>hept-5-ene-3-carboxylate with aroyl chloride and the subsequent hydrolysis of the ester group provided 2-aroyl-2-azabicyclo<2.2.1>hept-5-ene-3-carboxylic acid derivatives, which underwent a stereospecific rearrange

Full text of DOI:10.1246/bcsj.65.61

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