Electrophile Induced Reactions of Medium Ring Vinyl- and 1,2-Epoxy-silanes and Related Compounds

DOI: 10.1039/c39920001575

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Journal of the Chemical Society. Chemical communications p. 1575 - 1577 (1992)

Update date:2022-08-02

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Authors:

Wells, Adam P.

Riches, Bruce H.

Kitching, William

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Article abstract of DOI:10.1039/c39920001575

Deuterium labelling studies confirm extensive trans-annular participation in acidolysis, acetylation and brominolysis of 1,2-epoxy-1-trimethylsilylcyclooctane and (E)-1-trimethylsilylcyclooctene, and require revision of previous mechanistic proposals.

Full text of DOI:10.1039/c39920001575

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