Angewandte Chemie - International Edition p. 11605 - 11610 (2014)
Update date:2022-08-05
Topics: Intermediates Isomerization Rhodium-Catalyzed Cyclic Imines Nucleophilic allylation
Hepburn, Hamish B.
Lam, Hon Wai
Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained using chiral diene-rhodium complexes. Rhodium dance: Allylrhodium species generated from potassium allyltrifluoroborates can undergo isomerization by a 1,4-rhodium(I) migration to give more complex isomers, which then react with cyclic imines to provide products with up to three new stereochemical elements. High enantioselectivities are obtained with chiral diene-rhodium complexes.
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