A raney-cobalt-mediated tandem reductive cyclization route to the 1,5-methanoazocino[4,3-b]indole framework of the uleine and strychnos alkaloids

DOI: 10.1021/jo302132d

Source and publish data:

Journal of Organic Chemistry p. 10773 - 10781 (2012)

Update date:2022-08-03

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Authors:

Reekie, Tristan A.

Banwell, Martin G.

Willis, Anthony C.

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Article abstract of DOI:10.1021/jo302132d

The readily accessible enones 8, 17, and 18 undergo 2-fold reductive cyclization reactions upon exposure to hydrogen in the presence of Raney-cobalt and thereby afford compounds 11 (72%), 19 (47%), and 20 (84%), respectively. These products embody the ABC

Full text of DOI:10.1021/jo302132d

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