Nucleosides and nucleotides. 124. Chemical reactivity of the sugar moiety of 2'-deoxy-2'-methylidene pyrimidine nucleosides: Synthesis of 3'-amino-2',3'-dideoxy-2'-methylidene pyrimidine nucleosides via [2,3]-sigmatropic rearrangement of allylic selenides

DOI: 10.1016/S0040-4020(01)80786-9

Source and publish data:

Tetrahedron p. 689 - 700 (1994)

Update date:2022-08-06

Topics:

Authors:

Hassan Hassan

Shuto Shuto

Matsuda Matsuda

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Article abstract of DOI:10.1016/S0040-4020(01)80786-9

Nucleophilic substitution reactions of an allyl alcohol system in the 2'-deoxy-2'-methylidene pyrimidine nucleosides with various nucleophiles were investigated. The allyl alcohol system reacted with softer nucleophiles such as azide, thiophenoxide, and i

Full text of DOI:10.1016/S0040-4020(01)80786-9

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