Addition of 1-(α-Alkoxybenzyl)benzotriazoles to Enol Ethers. New Routes to 1,3-Diethers

DOI: 10.1021/jo00044a030

Source and publish data:

Journal of Organic Chemistry p. 4925 - 4931 (1992)

Update date:2022-07-30

Topics:

Authors:

Katritzky, Alan R.

Rachwal, Stanislaw

Rachwal, Bogumila

Steel, Peter J.

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Article abstract of DOI:10.1021/jo00044a030

1-(α-Alkoxybenzyl)benzotriazoles undergo reversible ionization in solution to a benzotriazolyl anion (Bt^-) and carboxonium cations PhCH:O⁺R.These cations can attack the β carbon of enol ethers to give cation adducts which add the Bt<

Full text of DOI:10.1021/jo00044a030

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