Binding studies on internal immunodeterminants: synthesis of β-(1->6)-linked oligosaccharide methyl glycosides having one to four internal D-galactopyranosyl residues flanked by gentiobiose residues

Article abstract of DOI:10.1016/S0008-6215(00)90575-5

The oligosaccharide glycosides β-D-Glcp-(1->6)-β-D-Glcp-(1->6)-<(β-D-Galp-(1->6)>n-β-D-Glcp-(1->6)-β-D-Glcp-1->OMe (n=1-4) were prepared by a convergent block synthesis.Haloacetyl, tert-butyldiphenylsilyl, and dimethylthexylsilyl groups were used as tempo