Journal of Organometallic Chemistry p. 49 - 61 (1992)
Update date:2022-08-04
Topics:
Castel, A.
Riviere, P.
Satge, J.
Desor, D.
The new aryldihydrogermyllithium complexes RH2GeLi (R = Ph, Mes) are prepared, in good yields, by metallation of the parent trihydrogermane with t-butyllithium in THF.They are characterized by alkylation reactions with MeI.Some germylation reactions are reported: they lead to the formation of new functional aryldihydrogermanes and aryldigermanes by a nucleophilic substitution.These aryldihydrogermyllithium complexes react also with acyl chlorides RCOCl (R = Ph, Mes) to give new diacyl- and triacyl-germanes.These easily add to the carbonyl group of aromatic aldehydes, thereby giving the corresponding α-germyl alcohols.
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
website:http://www.guarson.com
Contact:+86-523-88059600,+86-13805268803
Address:Room B1006,Yafang Building,Jiangyan Avenue,Jiangyan District, Taizhou City,Jiangsu,China
Beijing Apis Biotechnology Co., Ltd.
Contact:86-010-67856775-8551
Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Shandong Dayi Chemical Co., Ltd.
website:http://www.dayi.com.cn
Contact:+86- 535-7388728. 15306386031
Address:No 1 Danya west road, Laiyang City, Shandong province
Nanjing Ruizhi Industry & Technologh Co.，Ltd.
Contact:+86-25-86808110
Address:441-4-A5,NO.12 Longzang Avenue,Yuhuatai District,210039,Nanjing
Doi:10.1016/j.tetlet.2006.04.118
(2006)Doi:10.1039/c3cc42431f
(2013)Doi:10.1016/S0040-4020(01)80020-X
(1992)Doi:10.1016/0031-9422(92)80294-O
(1992)Doi:10.1021/jm400364h
(2013)Doi:10.1021/ol401214f
(2013)
