Oxidative decarboxylation of mandelate ethers and α-substituted phenylacetates via dioxetanone generation

DOI: 10.1016/S0040-4039(00)79133-7

Source and publish data:

Tetrahedron Letters p. 5205 - 5208 (1992)

Update date:2022-07-30

Topics:

Authors:

Heckmann

Alayrac Alayrac

Mioskowski

Chandrasekhar

Falck Falck

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79133-7

Mandelate ethers are oxidatively decarboxylated via in situ generated dioxetanones using (t)BuOK and air at ambient temperature leading, after hydrolysis, to the benzoic acid and the corresponding alcohol. The reaction can be extended to α-substituted phenylacetates.

Full text of DOI:10.1016/S0040-4039(00)79133-7

Products guided by the article

Product name:2-Hexanol, 1,1-bis(1-methylethoxy)-, (S)-

Cas No:144297-21-2

R&D Labs maybe for 144297-21-2

Hisyntech Corporation Limited

Contact:0086-22-23410962

Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd
Lian Xing Chemical Co.,Ltd.

Contact:0792-8228321

Address:10TH Floor No.121 binjiang Road Xunyang District
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin

Relevant to this article

Practical selective hydrogenation of α-fluorinated esters with bifunctional pincer-type ruthenium(II) catalysts leading to fluorinated alcohols or fluoral hemiacetals

Doi:10.1021/ja403852e
(2013)
Steric effect of a bulky 6-substituent in the I⁺-promoted glycosylation with pent-4-enyl and thioethyl glycosides

Doi:10.1016/0008-6215(92)80066-A
(1992)
Exploiting the dual role of ethynylbenziodoxolones in gold-catalyzed C(sp)-C(sp) cross-coupling reactions

Doi:10.1039/c7cc04283c
(2017)
Synthesis of 25X-BOMes and 25X-NBOHs (X = H, I, Br) for pharmacological studies and as reference standards for forensic purposes

Doi:10.1016/j.tetlet.2020.152804
(2021)
On triazoles. XL [1]. Non catalytic dehalogenation of some 5-chloro- 1,2,4-triazolo[1,5-a]pyrimidine derivatives

Doi:10.1002/jhet.5570360515
(1999)
Enzyme-Catalysed Hydrolysis of N-Benzyloxycarbonyl-cis-2,6-(acetoxymethyl)piperidine. A Facile Route to Optically Active Piperidines

Doi:10.1016/S0957-4166(00)86034-6
(1992)

Article Doi