Oxidative decarboxylation of mandelate ethers and α-substituted phenylacetates via dioxetanone generation

DOI: 10.1016/S0040-4039(00)79133-7

Source and publish data:

Tetrahedron Letters p. 5205 - 5208 (1992)

Update date:2022-07-30

Topics:

Authors:

Heckmann

Alayrac Alayrac

Mioskowski

Chandrasekhar

Falck Falck

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Article abstract of DOI:10.1016/S0040-4039(00)79133-7

Mandelate ethers are oxidatively decarboxylated via in situ generated dioxetanones using (t)BuOK and air at ambient temperature leading, after hydrolysis, to the benzoic acid and the corresponding alcohol. The reaction can be extended to α-substituted phenylacetates.

Full text of DOI:10.1016/S0040-4039(00)79133-7

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