Oxidative decarboxylation of mandelate ethers and α-substituted phenylacetates via dioxetanone generation

DOI: 10.1016/S0040-4039(00)79133-7

Source and publish data:

Tetrahedron Letters p. 5205 - 5208 (1992)

Update date:2022-07-30

Topics:

Authors:

Heckmann

Alayrac Alayrac

Mioskowski

Chandrasekhar

Falck Falck

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79133-7

Mandelate ethers are oxidatively decarboxylated via in situ generated dioxetanones using (t)BuOK and air at ambient temperature leading, after hydrolysis, to the benzoic acid and the corresponding alcohol. The reaction can be extended to α-substituted phenylacetates.

Full text of DOI:10.1016/S0040-4039(00)79133-7

Products guided by the article

Product name:2-Hexanol, 1,1-bis(1-methylethoxy)-, (S)-

Cas No:144297-21-2

R&D Labs maybe for 144297-21-2

Shenyang Mole pharmaceutical Technology Development Co.,Ltd

Contact:+86-24-31204918/13889278616

Address:No.44, wanliutang road, shenhe District of Shenyang
Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Sinochem Jiangsu Co.,Ltd.

Contact:86-25-51817806

Address:No. 216, middle longpan road, jincheng tower, floor 21-22, nanjing ,china
Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
Cangzhou Senary Chemical Science-tech Co., Ltd

Contact:+86-317-3563899, 3563699

Address:168 Jinde Road, Cangzhou, Hebei, China

Relevant to this article

Practical selective hydrogenation of α-fluorinated esters with bifunctional pincer-type ruthenium(II) catalysts leading to fluorinated alcohols or fluoral hemiacetals

Doi:10.1021/ja403852e
(2013)
Steric effect of a bulky 6-substituent in the I⁺-promoted glycosylation with pent-4-enyl and thioethyl glycosides

Doi:10.1016/0008-6215(92)80066-A
(1992)
Exploiting the dual role of ethynylbenziodoxolones in gold-catalyzed C(sp)-C(sp) cross-coupling reactions

Doi:10.1039/c7cc04283c
(2017)
Synthesis of 25X-BOMes and 25X-NBOHs (X = H, I, Br) for pharmacological studies and as reference standards for forensic purposes

Doi:10.1016/j.tetlet.2020.152804
(2021)
On triazoles. XL [1]. Non catalytic dehalogenation of some 5-chloro- 1,2,4-triazolo[1,5-a]pyrimidine derivatives

Doi:10.1002/jhet.5570360515
(1999)
Enzyme-Catalysed Hydrolysis of N-Benzyloxycarbonyl-cis-2,6-(acetoxymethyl)piperidine. A Facile Route to Optically Active Piperidines

Doi:10.1016/S0957-4166(00)86034-6
(1992)

Article Doi