Oxidative decarboxylation of mandelate ethers and α-substituted phenylacetates via dioxetanone generation

DOI: 10.1016/S0040-4039(00)79133-7

Source and publish data:

Tetrahedron Letters p. 5205 - 5208 (1992)

Update date:2022-07-30

Topics:

Authors:

Heckmann

Alayrac Alayrac

Mioskowski

Chandrasekhar

Falck Falck

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79133-7

Mandelate ethers are oxidatively decarboxylated via in situ generated dioxetanones using (t)BuOK and air at ambient temperature leading, after hydrolysis, to the benzoic acid and the corresponding alcohol. The reaction can be extended to α-substituted phenylacetates.

Full text of DOI:10.1016/S0040-4039(00)79133-7

Products guided by the article

Product name:2-Hexanol, 1,1-bis(1-methylethoxy)-, (S)-

Cas No:144297-21-2

R&D Labs maybe for 144297-21-2

SuZhou LaiTeou

Contact:+86-0512-88957371

Address:shanghai
Weifang Ocean Trading Co., Ltd.

Contact:+86-536-2081155

Address:Room2606, Yuqing Building, 518#, Yuquan Road, High-tech Development Zone, Weifang City, Shandong Province, China
Yancheng Creator Chemical Co., Ltd

Contact:0086-515-88710008 88710068 88710858 88710868

Address:No.21 Renming Road, Longgang Town, Yandu County,Yancheng City
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203
Hybio Pharmaceutica Co.,Ltd

Contact:+86 755 26588093

Address:No.9 Linkong West Street, Hengdian Street, Huangpi District, Wuhan City, China.

Relevant to this article

Practical selective hydrogenation of α-fluorinated esters with bifunctional pincer-type ruthenium(II) catalysts leading to fluorinated alcohols or fluoral hemiacetals

Doi:10.1021/ja403852e
(2013)
Steric effect of a bulky 6-substituent in the I⁺-promoted glycosylation with pent-4-enyl and thioethyl glycosides

Doi:10.1016/0008-6215(92)80066-A
(1992)
Exploiting the dual role of ethynylbenziodoxolones in gold-catalyzed C(sp)-C(sp) cross-coupling reactions

Doi:10.1039/c7cc04283c
(2017)
Synthesis of 25X-BOMes and 25X-NBOHs (X = H, I, Br) for pharmacological studies and as reference standards for forensic purposes

Doi:10.1016/j.tetlet.2020.152804
(2021)
On triazoles. XL [1]. Non catalytic dehalogenation of some 5-chloro- 1,2,4-triazolo[1,5-a]pyrimidine derivatives

Doi:10.1002/jhet.5570360515
(1999)
Enzyme-Catalysed Hydrolysis of N-Benzyloxycarbonyl-cis-2,6-(acetoxymethyl)piperidine. A Facile Route to Optically Active Piperidines

Doi:10.1016/S0957-4166(00)86034-6
(1992)

Article Doi