Osmium-Mediated Asymmetric Synthesis of Glycosyl-myo-inositols from Oxanorboranes

DOI: 10.1021/jo00049a007

Source and publish data:

Journal of Organic Chemistry p. 6097 - 6099 (1992)

Update date:2022-08-04

Topics: Asymmetric synthesis Osmium

Authors:

Arjona, Odon

Candilejo, Augustin

Dios, Alfonso de

Pradilla, Roberto Fernadez de la

Plumet, Joaquin

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Article abstract of DOI:10.1021/jo00049a007

The osmium-catalyzed cis-dihydroxylation of "symmetrical" 4-O-glycosyl-1-O-acetyl-conduritol B derivatives occurs syn to the allylic acetate with high ?-facial selectivity and affords glycosyl-myo-inositols in excellent yield.

Full text of DOI:10.1021/jo00049a007

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