The squalestatins: C-3 decarboxylation studies and rearrangement to the 6,8-dioxabicyclo [3.2.1]octane ring system

DOI: 10.1016/S0040-4039(00)61752-5

Source and publish data:

Tetrahedron Letters p. 6143 - 6146 (1993)

Update date:2022-07-30

Topics: Rearrangement squalestatins

Authors:

Chan, Chuen

Inglis, Graham Ga

Procopiou, Panayiotis A.

Ross, Barry C.

Srikantha, Anton Rp

Watson, Nigel S.

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Article abstract of DOI:10.1016/S0040-4039(00)61752-5

3-Decarboxy squalestatins 3 and 4 were synthesised via photolysis of t-butyl peroxyester 7. Lactol 10 was isolated unexpectedly from both HCl-dioxan cleavage of 8, a by-product of the photolysis, and attempted Barton decarboxylation of 6. In TFA under anh

Full text of DOI:10.1016/S0040-4039(00)61752-5

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