N-Arylurethane neighboring group participation during solvolysis of 3-methoxy-17-N-phenylcarbamoyloxy-16-p-tolylsulfonyloxymethylestra-1, 3,5(10)-triene stereoisomers

DOI: 10.1016/S0040-4020(01)85620-9

Source and publish data:

Tetrahedron p. 9305 - 9314 (1992)

Update date:2022-08-05

Topics:

Authors:

Hackler Hackler

Schneider

Sohar Sohar

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Article abstract of DOI:10.1016/S0040-4020(01)85620-9

During alkaline methanolysis of the four stereoisomers 1-4 of 3-methoxy-17-N-phenylcarbamoyloxy-16-p-tolylsulfonyloxymethylestra-1, 3,5(10)-triene, a clycization taken place, in the course of which the N-phenyl-tetrahydrooxazin-2-one derivatives 5-8 are f

Full text of DOI:10.1016/S0040-4020(01)85620-9

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