Grignard-type Addition of Alkenyl- and Alkylzirconocene Chloride to Aldehyde: Remarkable Catalytic Acceleration Effect of AgClO4

DOI: 10.1016/S0040-4039(00)61101-2

Source and publish data:

Tetrahedron Letters p. 5965 - 5968 (1992)

Update date:2022-08-03

Topics:

Authors:

Maeta, Hideki

Hashimoto, Takeshi

Hasegawa, Takayuki

Suzuki, Keisuke

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Article abstract of DOI:10.1016/S0040-4039(00)61101-2

Nucleophilic addition of alkenylzirconocene chloride to aldehyde, which is ordinarily a slow reaction, is remarkably accelerated by a catalytic amount of AgClO4.The rate acceleration effect is also valid for the alkyl congener, Cp2Zr(Cl)R.

Full text of DOI:10.1016/S0040-4039(00)61101-2

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