Tetrahedron p. 3655 - 3664 (1995)
Update date:2022-08-04
Topics: Addition Regioselective Grignard Reagent Experimental
Andresen, Geir
Gundersen, Lise-Lotte
Lundmark, Max
Rise, Frode
Sundell, Staffan
Treatment of 6-ethoxy-1,3,6,7-tetrahydro-1,3,7-tribenzyl-2H-purin-2-one with trimethylchlorosilane gave a stable tribenzylated 2-oxopurinium salt, which selectively added Grignard reagents in the 6-position.The structure of the adducts were established fr
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