Regioselective Addition of Grignard Reagents to a 2-Oxopurinium Salt

DOI: 10.1016/0040-4020(95)00080-R

Source and publish data:

Tetrahedron p. 3655 - 3664 (1995)

Update date:2022-08-04

Topics: Addition Regioselective Grignard Reagent Experimental

Authors:

Andresen, Geir

Gundersen, Lise-Lotte

Lundmark, Max

Rise, Frode

Sundell, Staffan

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Article abstract of DOI:10.1016/0040-4020(95)00080-R

Treatment of 6-ethoxy-1,3,6,7-tetrahydro-1,3,7-tribenzyl-2H-purin-2-one with trimethylchlorosilane gave a stable tribenzylated 2-oxopurinium salt, which selectively added Grignard reagents in the 6-position.The structure of the adducts were established fr

Full text of DOI:10.1016/0040-4020(95)00080-R

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