Application of the 2,3-sigmatropic rearrangement of β-sulfonyl acetylenic carbinols toward the synthesis of 1,4-bis(phenylsulfonyl)-1,3-butadienes

DOI: 10.1016/S0040-4039(00)60172-7

Source and publish data:

Tetrahedron Letters p. 7303 - 7306 (1992)

Update date:2022-08-02

Topics:

Authors:

Wang Wang

Rodriguez

Padwa Padwa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)60172-7

Sulfenic esters of β-sulfur substituted acetylenic carbinols undergo 2,3-sigmatropic rearrangement to produce allenylic sulfoxides which were converted to 1,4-bis(phenylsulfonyl)-1,3-dienes of α,β-unsaturated ketones.

Full text of DOI:10.1016/S0040-4039(00)60172-7

Products guided by the article

Product name:2-Benzenesulfonyl-1-ethynyl-cyclohexanol

Cas No:150587-50-1

R&D Labs maybe for 150587-50-1

Anhui Qingyun Pharmaceutical and Chemical Co.,Ltd

Contact:+86-551-63633067

Address:Shuangfeng Road Hefei Anhui
Winchem Industrial Co. Ltd.(expird)

Contact:86-574-83851061 86-574-87083208

Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Qida Chemical Co., Ltd.(expird)

Contact:+86-25-8776 0031

Address:3-2001 Jiaye Int'l Town, 158 Lushan Road,Nanjing, 210019, China
Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
Tianjin Chemsyntech Chemical Co., Ltd

Contact:+86-22-60872258

Address:Haitai green industry base in Tianjin, K1,5-601

Relevant to this article

Synthesis of (R)- and (S)-3-(tert-butyldimethylsilyloxy)-1-pyrroline N- oxides - Chiral nitrones for synthesis of biologically active pyrrolidine derivative, Geissman-Waiss lactone

Doi:10.1016/S0040-4039(98)00333-5
(1998)
A convenient method for synthesis of Fmoc-amino acid p-nitroanilides based on isobutyl chloroformate as condensation agent

Doi:10.1016/S0040-4039(00)60527-0
(1993)
Towards the total synthesis of the anti-trypanosomal macrolide, Actinoallolides: Construction of a key linear intermediate

Doi:10.1016/j.tetlet.2015.12.022
(2016)
trans-4-Methyl-3-imidazoyl pyrrolidine as a potent, highly selective histamine H₃ receptor agonist in vivo

Doi:10.1016/S0960-894X(98)00020-1
(1998)
Use of allylzinc halide as a source of halide: Differential addition of nucleophiles to Ts-aziridines and aldehydes under similar reaction conditions

Doi:10.1016/j.tetlet.2018.12.027
(2019)
Enzymatic resolution of N,N-dialkyl-3-hydroxy-4-pentenamides, unsuccessful in resolution by the Katsuki-Sharpless asymmetric epoxidation

Doi:10.1016/S0957-4166(00)80150-0
(1993)

Article Doi