Application of the 2,3-sigmatropic rearrangement of β-sulfonyl acetylenic carbinols toward the synthesis of 1,4-bis(phenylsulfonyl)-1,3-butadienes

DOI: 10.1016/S0040-4039(00)60172-7

Source and publish data:

Tetrahedron Letters p. 7303 - 7306 (1992)

Update date:2022-08-02

Topics:

Authors:

Wang Wang

Rodriguez

Padwa Padwa

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Article abstract of DOI:10.1016/S0040-4039(00)60172-7

Sulfenic esters of β-sulfur substituted acetylenic carbinols undergo 2,3-sigmatropic rearrangement to produce allenylic sulfoxides which were converted to 1,4-bis(phenylsulfonyl)-1,3-dienes of α,β-unsaturated ketones.

Full text of DOI:10.1016/S0040-4039(00)60172-7

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