Enantioselective Synthesis of Homoallylic Amines. Evidence of Reversible Addition of Allylzinc Bromide to Aromatic Imines Derived from (S)-Valine Methyl Ester and (S)-Valinol

DOI: 10.1039/c39930001542

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1542 - 1544 (1993)

Update date:2022-08-03

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Authors:

Bocoum, Allaye

Savoia, Diego

Umani-Ronchi, Achille

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Article abstract of DOI:10.1039/c39930001542

The reaction of aromatic and aliphatic imines derived from (S)-valine methyl ester and (S)-valinol with allyl bromide and zinc in tetrahydrofuran affords homoallylic amines with up to 100percent diastereoisomeric excess (d.e.), but in the case of the arom

Full text of DOI:10.1039/c39930001542

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Product name:Methyl N-<(4S)-4-(4'-methoxyphenyl)but-1-en-4-yl>-(S)-valinate

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