Palladium(II) promoted O-glycosylation involving 1-thio-2-enosides and 3-thio-1-enoses

DOI: 10.1016/0040-4039(94)88180-4

Source and publish data:

Tetrahedron Letters p. 125 - 128 (1994)

Update date:2022-08-03

Topics:

Authors:

Takeda, Kazuyoshi

Nakamura, Hiroko

Ayabe, Akira

Akiyama, Akira

Harigaya, Yoshihiro

Mizuno, Yoshihisa

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Article abstract of DOI:10.1016/0040-4039(94)88180-4

O-glycosylation of thioglycosyl donors, 2,3-dideoxy-hex-l-thio-2-enopyranosides, 1,2-dideoxy-hex-3-thio-1-nopyranoses and 2-pyridyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranoside was achieved by use of a Pd(II) activator which was prepared from bis(acetonitrile)dichloropalladium(II)(Pd(CH₃CN)₂Cl ₂) and silver triflate (AgOTf).

Full text of DOI:10.1016/0040-4039(94)88180-4

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