Synthese und Koordinationsverhalten von Di(1-phenyl-ethinyl)-Sulfan

Article abstract of DOI:10.1016/0022-328X(94)88050-6

The synthesis of S(C<*>CPh)2 (III) is described.Compound III reacts with one equivalent octacarbonyldicobalt (IV) to yield (PhC<*>C)S<(η²-C<*>CPh)Co2(CO)6> (V); with another equivalent of Co2(CO)8 (IV) the di-coordinated compound S<(η²