Thermal Z-E Isomerization of Azobenzenes. The Pressure, Solvent, and Substituent Effects

DOI: 10.1021/jo00197a011

Source and publish data:

Journal of Organic Chemistry p. 4387 - 4391 (1984)

Update date:2022-07-31

Topics:

Authors:

Asano, Tsutomu

Okada, Toshio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00197a011

The rates of thermal Z-E isomerization of 4-(dimethylamino)-4'-nitroazobenzene were measured in a variety of solvents, and the Kirkwood plot revealed that the rate constant increase is much larger in polar solvents than expected from the continuum theory.

Full text of DOI:10.1021/jo00197a011

Products guided by the article

Product name:Diazene, (4-nitrophenyl)phenyl-, (Z)-

Cas No:15516-73-1

R&D Labs maybe for 15516-73-1

Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Landz International Company Ltd.

Contact:0086-21-58891610

Address:985 Dongfang Road, Pudong, Shanghai 200122 China
Zha Yan

Contact:+86-13914766747

Address:Floors 21&22, Jin Cheng Tower, No. 216 Middle Longpan Road, Nanjing
Shanghai Cheerchem Co., Ltd.

Contact:86-21-50966856

Address:Building 5,300 Chuanzhan Road,Pudong New District,Shanghai
Foreschem Co., Ltd

Contact:+86-533-3112891

Address:zibo

Relevant to this article

ANTIHISTAMINE SUBSTANCES. TRICYCLIC ANALOGUES OF N-(4,4-DIPHENYL-3-BUTENE-1-YL)NIPECOTIC ACID AND SOME RELATED COMPOUNDS

Doi:10.1135/cccc19940667
(1994)
Regioselective Synthesis of 2-Arylindoles via Palladium-Catalyzed Cyclization of Phenylglyoxal and 2-Anilinoacetophenones with Anilines

Doi:10.1002/ejoc.201900394
(2019)
Na⁺ ion templated threading of Oligo(ethylene glycol) chains through BPX26C6 Allows synthesis of [2]rotaxanes under solvent-free conditions

Doi:10.1021/ol403602j
(2014)
Modular automated solid phase synthesis of dermatan sulfate oligosaccharides

Doi:10.1039/c3cc48860h
(2014)
Reactions of P(III) chlorides with aldehydes: I. Synthesis of primary intermediates of the reactions of aliphatic aldehydes with P(III) chlorides possessing electrophilic properties

Doi:10.1134/S1070363213120104
()
Heteronuclear iron-ruthenium complexes containing bridging allenyl and allenylcarbonyl ligands

Doi:10.1021/om00017a066
(1994)

Article Doi