Thermal Z-E Isomerization of Azobenzenes. The Pressure, Solvent, and Substituent Effects

DOI: 10.1021/jo00197a011

Source and publish data:

Journal of Organic Chemistry p. 4387 - 4391 (1984)

Update date:2022-07-31

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Authors:

Asano, Tsutomu

Okada, Toshio

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Article abstract of DOI:10.1021/jo00197a011

The rates of thermal Z-E isomerization of 4-(dimethylamino)-4'-nitroazobenzene were measured in a variety of solvents, and the Kirkwood plot revealed that the rate constant increase is much larger in polar solvents than expected from the continuum theory.

Full text of DOI:10.1021/jo00197a011

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